Tetrahedron p. 2275 - 2282 (1984)
Update date:2022-09-26
Topics:
Still, W. Clark
MacPherson, Lawrence J.
Harada, Toshiro
Callahan, James F.
Rheingold, Arnold L.
The conformations of macrocyclic intermediates provide a useful medium through which distant chiral centers may control chemical reactions.In this paper, we show that macrocycles made by cyclization of simple acyclic starting materials with an auxiliary spacer may be used to prepare stereochemically complex acyclic products.
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