
Synthetic Communications p. 1975 - 1983 (2000)
Update date:2022-08-03
Topics:
De Mattos, Marcio C. S.
Sanseverino, Antonio Manzolillo
Several methodologies to produce α-terpinyl chloride from 'hydrochlorination' of limonene were studied and the best results were obtained by reaction with 0.5 mol equiv. SOCl2 in SiO2/CH2Cl2. Using this methodology (R)- and (S)-α-terpinyl chloride can easily be prepared in good yields from (R)- and (S)-limonene, respectively.
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Doi:10.1016/S0040-4039(00)93737-7
(1976)Doi:10.1016/j.dyepig.2013.12.018
(2014)Doi:10.1002/adsc.200505147
(2005)Doi:10.1002/chem.201100618
(2011)Doi:10.1021/ja002138n
(2000)Doi:10.1021/jo00878a014
(1976)