
Tetrahedron Letters p. 5121 - 5124 (1992)
Update date:2022-08-05
Topics:
Cardellicchio, Cosimo
Fiandanese, Vito
Naso, Francesco
Scilimati, Antonio
Optically active bromovinyl aryl sulfoxides were subjected to reactions with phenyl- or alkyl-magnesium compounds, with the production of optically active diaryl or aryl alkyl sulfoxides, with inversion of configuration. The enantiospecificity of the process was found to be 98-100%.
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(2014)