Is I2 or MeCN the Better Base to coordinate the Iodine Monocation, I+? The Hard-Soft Acid-Base Principle in Preparative Inorganic Chemistry

DOI: 10.1039/c39900001433

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1433 - 1434 (1990)

Update date:2022-08-05

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Authors:

Gowik, Petra K.

Klapoetke, Thomas M.

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Article abstract of DOI:10.1039/c39900001433

The quantitative formation of MeCNI⁺ from MeCN and I3⁺ in SO2 and the back reaction (MeCNI⁺ + I2 gives MeCN + I3⁺) are discussed on the basis of the HSAB principle.

Full text of DOI:10.1039/c39900001433

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