Tetrahedron p. 6021 - 6032 (1990)
Update date:2022-07-30
Topics:
Calmes, Monique
Daunis, Jacques
Ismaili, Habiba
Jacquier, Robert
Koudou, Jean
et al.
A polyacrylic resin with pendant chirality has been used as a chiral auxiliary.The prochiral ester enolate, reversibly linked to the polymer chain via a Schiff base, is surrounded by chiral pendants, allowing supramolecular asymmetric induction to occur.Amino acids with enantiomeric excesses up to 88-89percent could be synthesized from supported glycine t-butyl ester enolate by reaction with alkyl halides.Enantioselective protonation depends on the initial configuration of the supported amino acid.Alanine was obtained in 90percent ee by repetitive asymmetric protonation.
View MoreWuhan Better Organic Technology Inc.
Contact:13307163183
Address:Wuhan Economic&Technology Development Zone, Hubei
Contact:0086-27-83607103/83642615
Address:No.498, Jianshe Ave, Wuhan, China
Hangzhou Dingyan Chem Co., Ltd
website:http://www.dingyanchem.com
Contact:86-571-87157530
Address:RM.1118,NO.1 Building, Baiyun Tower,Jianggan Area, Hangzhou city, China,310004
Contact:+86-633-8332928
Address:No.1,Huanghai Yilu.Rizhao,Shandong
Contact:+86 21 5017 5386
Address:No 999,Jiangyue Rd, Minhang Dist ,201114,Shanghai ,China
Doi:10.1016/j.bmcl.2006.11.078
(2007)Doi:10.1021/acs.joc.7b01623
(2017)Doi:10.1039/DT9780001032
()Doi:10.1016/S0960-894X(02)00479-1
(2002)Doi:10.1016/j.tetlet.2005.09.003
(2005)Doi:10.1039/P29760001157
(1976)
