Journal of the Chemical Society. Chemical communications p. 1835 - 1837 (1989)
Update date:2022-08-04
Topics:
Williams, Ffrancon
Guo, Quing-Xiang
Kolb, Thomas M.
Nelsen, Stephen F.
The title radical cation (2) has been detected and characterized by ESR spectroscopy as the initial product of the radiolytic oxidation of bicyclo<2.1.0>pentane (1) in the CF3CCl3, CF2ClCFCl2, CFCl2CFCl2, and CFCl3 matrices at 77 K, its formation being accompanied by retention of Cs symmetry with the development of planar carbon centres at the original bridgehead positions; (2) undergoes subsequent isomerization to the cyclopentene radical cation (3) by intramolecular hydrogen transfer at ca. 100 K.
View MoreContact:021-36356756
Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Hangzhou Donglou Bio-nutrient Co., Ltd.
Contact:+86-571-82225795,13967112289
Address:Louta Town, Xiaoshan,Hangzhou,Zhejiang
Shanghai He Yang International Trading Co., Ltd.
Contact:+86-21-52043598
Address:Room 816, Blag.5, No.58 Huachi Road
Shanxi Tongji Pharmaceuticals Co., Ltd.
Contact:+86-359-3024784
Address:Xikuang South Road, Ruicheng County , Shanxi
Shenyang Mole pharmaceutical Technology Development Co.,Ltd
Contact:+86-24-31204918/13889278616
Address:No.44, wanliutang road, shenhe District of Shenyang
Doi:10.1023/A:1020343221719
(2002)Doi:10.1055/s-1977-24415
(1977)Doi:10.1016/j.bmcl.2004.03.052
(2004)Doi:10.1016/S0022-328X(00)86326-3
(1968)Doi:10.1021/acs.langmuir.5b02101
(2015)Doi:10.1016/S0960-894X(03)00538-9
(2003)
