Journal of the Chemical Society. Chemical communications p. 1835 - 1837 (1989)
Update date:2022-08-04
Topics:
Williams, Ffrancon
Guo, Quing-Xiang
Kolb, Thomas M.
Nelsen, Stephen F.
The title radical cation (2) has been detected and characterized by ESR spectroscopy as the initial product of the radiolytic oxidation of bicyclo<2.1.0>pentane (1) in the CF3CCl3, CF2ClCFCl2, CFCl2CFCl2, and CFCl3 matrices at 77 K, its formation being accompanied by retention of Cs symmetry with the development of planar carbon centres at the original bridgehead positions; (2) undergoes subsequent isomerization to the cyclopentene radical cation (3) by intramolecular hydrogen transfer at ca. 100 K.
View MoreNanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Contact:86-513-84128750/13773795976
Address:No.48.Youyi West Road ,Rudong Development Zone,Jiangsu Province,China
website:http://www.synchemie.com/
Contact:+86-574-87642758
Address:Room 901, Yinyi Bund Building， 132 Renmin Road
Contact:Tel:+86-29-88764861 Fax:+86-29-88764861
Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China
Contact:0091-265-2313036
Address:311, ATLANTIS HEIGHTS SARABHAI MAIN ROAD,VADIWADI ,VADODARA
Doi:10.1023/A:1020343221719
(2002)Doi:10.1055/s-1977-24415
(1977)Doi:10.1016/j.bmcl.2004.03.052
(2004)Doi:10.1016/S0022-328X(00)86326-3
(1968)Doi:10.1021/acs.langmuir.5b02101
(2015)Doi:10.1016/S0960-894X(03)00538-9
(2003)
