Tetrahedron p. 4270 - 4278 (2014)
Update date:2022-09-26
Topics:
Lu, Zhan
Parrish, Jonathan D.
Yoon, Tehshik P.
We report that Ru(bpz)32+ is an excellent sensitizer for the photooxygenation of aryl cyclopropanes upon irradiation with visible light. The effectiveness of this photocatalyst enables the synthesis of a range of five-membered endoperoxides in excellent yield with quite low (0.5 mol %) catalyst loadings even when standard household light sources are utilized.
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