Allenyl Allylic Ethers: Synthesis and Thermal Rearrangements

DOI: 10.1021/jo00073a032

Source and publish data:

Journal of Organic Chemistry p. 5702 - 5708 (1993)

Update date:2022-09-26

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Authors:

Dulcere, Jean-Pierre

Crandall, Jack

Faure, Robert

Santelli, Maurice

Agati, Valerie

Mihoubi, Mohamed N.

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Article abstract of DOI:10.1021/jo00073a032

Application of the sequence halogenation/dehydrohalogenation/isomerization to alkenes 1a-g affords allenyl allylic ethers 5a-g.Thermal isomerizations of 5a,d,e proceed by Claisen rearrangement, while 5b,c,f,g are transformed by alternate modes of <2 + 2>c

Full text of DOI:10.1021/jo00073a032

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