Synthesis of homoallylic chiral tertiary alcohols via chelation-controlled diastereoselective nucleophilic addition on α-alkoxyketones: Application for the synthesis of the C1-C11 subunit of 8-epi-fostriecin

DOI: 10.1021/ol035516c

Source and publish data:

Organic Letters p. 3755 - 3757 (2003)

Update date:2022-07-29

Topics:

Authors:

Ramachandran, P. Veeraraghavan

Liu, Haipeng

Reddy, M. Venkat Ram

Brown, Herbert C.

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Article abstract of DOI:10.1021/ol035516c

(Matrix presented) Chiral β-syn-alkoxyhomoallylic alcohols derived from alkoxyallylboration of aldehydes upon oxidation provided the corresponding chiral ketones. Chelation-controlled nucleophilic addition to these ketones occurred in a highly stereoselec

Full text of DOI:10.1021/ol035516c

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