Carbolithiation of cinnamyl methyl ethers and 2-cinnamyl-2-methyl-1,3- dioxolane: High diastereoselectivity after electrophilic substitution

DOI: 10.1016/S0040-4020(99)00018-6

Source and publish data:

Tetrahedron p. 2609 - 2624 (1999)

Update date:2022-08-04

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Authors:

Mueck-Lichtenfeld, Christian

Ahlbrecht, Hubertus

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Article abstract of DOI:10.1016/S0040-4020(99)00018-6

The carbolithiation of cinnamyl methyl ether 4 with tert-butyllithium, benzyllithium, and allyllithium is achieved in good yields. Consecutive treatment with electrophiles yields in all three cases a good diastereoselectivity thus confirming earlier resul

Full text of DOI:10.1016/S0040-4020(99)00018-6

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