Tetrahedron p. 343 - 356 (1991)
Update date:2022-08-04
Topics:
Negishi, Ei-ichi
Yoshida, Takao
Abramovitch, Akiva
Lew, George
Williams, Robert M.
A highly selective and potentially general methodology for the synthesis of conjugated E,E- and E,Z-dienes, E-enynes, and E-1,2,3-butatrienes via hydroboration of alkynes is reported.The observed stereoselectivity was >98-99percent.
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Doi:10.1039/c6ob00993j
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