Strategies and methods for the attachment of amino acids and peptides to chiral [n]polynorbornane templates.

DOI: 10.1039/b301980b

Source and publish data:

Organic and biomolecular chemistry p. 1845 - 1851 (2003)

Update date:2022-08-02

Topics: Amino acids Chiral Peptides Experimental Strategies Attachment

Authors:

Pfeffer, Frederick M

Russell, Richard A

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Article abstract of DOI:10.1039/b301980b

A versatile synthesis of amino acid and peptide functionalised [n]polynorbornane scaffolds is described. The frameworks are constructed using the stereoselective and regioselective cycloaddition of suitably functionalised chiral cyclobutene epoxides with similar norbornenes. The strategies employed allow a range of topologies to be accessed and a number of regioselectively addressable linkage points to be accommodated.

Full text of DOI:10.1039/b301980b

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