Rhodium(III) biphasic and phase-transfer-catalyzed hydrogenolysis of chloroarenes under exceptionally mild conditions

DOI: 10.1021/om00051a063

Source and publish data:

Organometallics p. 1620 - 1622 (1991)

Update date:2022-07-31

Topics:

Authors:

Grushin, Vladimir V.

Alper, Howard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00051a063

The rhodium (III) complexes L₂Rh(H)Cl₂ [L = tricyclohexylphosphine or triisopropylphosphine] are excellent catalysts for the hydrogenolysis of chlorparenes. The reaction proceeds under biphasic [40% NaOH, PhCH₃] conditions

Full text of DOI:10.1021/om00051a063

Products guided by the article

Product name:HRhCl₂(tricyclohexylphosphine)2

Cas No:63736-69-6

R&D Labs maybe for 63736-69-6

Zibo Kunran Enterprises Co. LTD

website:http://www.kunranchem.com

Contact:0086 533 5200669

Address:No. 96 Jinjing Avenue, Zibo, Shandong, China
Evergreen Chemical Industry Ltd.

Contact:86-553-4918210

Address:6#2-602 Wanhaobailing
waho int'l company

Contact:+86-579-85206992

Address:No 451 chouzhou north road ,room 1106 int'l business center , yiwu ,china
Taiwan Surfactant Corp.

Contact:886 2 2541 0022

Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
RongCheng Tianyu Technology Co.,Ltd.

Contact:86-631-7519595

Address:220Ping Donghai Road RongChengCity,ShangDong Province China

Relevant to this article

Doi:10.1021/bi00749a001
(1973)
REGIOSELECTIVE ADDITION OF CARBONYL COMPOUNDS TO ISOPRENE COORDINATED TO Zr

Doi:10.1246/cl.1981.671
(1981)
Tricyclic benzoxazinones

Doi:10.1002/ardp.19813140610
(1981)
Doi:10.1039/jr9650004922
(1965)
Enantiodifferentiating Cis-Trans Photoisomerizations of 1,2-Diarylcyclopropanes and 2,3-Diphenyloxirane Sensitized by Chiral Aromatic Esters

Doi:10.1021/jo00059a032
(1993)
Exceptionally strong electronic coupling between [Mo₂] units linked by substituted dianionic quinones

Doi:10.1039/b710804d
(2008)

Article Doi