Rhodium(III) biphasic and phase-transfer-catalyzed hydrogenolysis of chloroarenes under exceptionally mild conditions

DOI: 10.1021/om00051a063

Source and publish data:

Organometallics p. 1620 - 1622 (1991)

Update date:2022-07-31

Topics:

Authors:

Grushin, Vladimir V.

Alper, Howard

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Article abstract of DOI:10.1021/om00051a063

The rhodium (III) complexes L₂Rh(H)Cl₂ [L = tricyclohexylphosphine or triisopropylphosphine] are excellent catalysts for the hydrogenolysis of chlorparenes. The reaction proceeds under biphasic [40% NaOH, PhCH₃] conditions

Full text of DOI:10.1021/om00051a063

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