Rhodium(III) biphasic and phase-transfer-catalyzed hydrogenolysis of chloroarenes under exceptionally mild conditions

DOI: 10.1021/om00051a063

Source and publish data:

Organometallics p. 1620 - 1622 (1991)

Update date:2022-07-31

Topics:

Authors:

Grushin, Vladimir V.

Alper, Howard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/om00051a063

The rhodium (III) complexes L₂Rh(H)Cl₂ [L = tricyclohexylphosphine or triisopropylphosphine] are excellent catalysts for the hydrogenolysis of chlorparenes. The reaction proceeds under biphasic [40% NaOH, PhCH₃] conditions

Full text of DOI:10.1021/om00051a063

Products guided by the article

Product name:HRhCl₂(tricyclohexylphosphine)2

Cas No:63736-69-6

R&D Labs maybe for 63736-69-6

Jining Shengrun Chemical Industry Co., Ltd.

Contact:+86-537-7121666 ,

Address:West Ring Road,Wenshang County Shandong Province
Guangxi Nanning Guangtai Agriculture Chemical Co.,Ltd

Contact:+86-771-2311266

Address:Room703,Building12, Software Park Phase II,NO.68,Keyuan Road,Nanning City,Guangxi,China
Shanghai Yanchu chemicals Co., Ltd

website:http://www.yanchuchem.com

Contact:0086 18601657701

Address:Room 1292, Building NO. 2, Lane 65, Huandong 1st Rd, Fengjing Town, Jinshan Distriction, shanghai
Xian Changyue Biological Technology Co., Ltd.

website:https://www.xachangyue.com/

Contact:+86-029-88211911

Address:Keji Road NO.70
GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China

Relevant to this article

Doi:10.1021/bi00749a001
(1973)
REGIOSELECTIVE ADDITION OF CARBONYL COMPOUNDS TO ISOPRENE COORDINATED TO Zr

Doi:10.1246/cl.1981.671
(1981)
Tricyclic benzoxazinones

Doi:10.1002/ardp.19813140610
(1981)
Doi:10.1039/jr9650004922
(1965)
Enantiodifferentiating Cis-Trans Photoisomerizations of 1,2-Diarylcyclopropanes and 2,3-Diphenyloxirane Sensitized by Chiral Aromatic Esters

Doi:10.1021/jo00059a032
(1993)
Exceptionally strong electronic coupling between [Mo₂] units linked by substituted dianionic quinones

Doi:10.1039/b710804d
(2008)

Article Doi