
Chemistry Letters p. 671 - 674 (1981)
Update date:2022-07-31
Topics:
Yasuda, Hajime
Kajihara, Yasushi
Mashima, Kazushi
Nagasuna, Kinya
Nakamura, Akira
ZrCp2(isoprene) reacts with aliphatic aldehydes, ketones or nitriles regioselectively on C1-carbon of the isoprene moiety to give novel 2-oxa- or 2-aza-metallacycles which release alcohols or ketones respectively on hydrolysis.In contrast, ZrCH3(η1
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Doi:10.1021/ja01213a501
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(1984)