REGIOSELECTIVE ADDITION OF CARBONYL COMPOUNDS TO ISOPRENE COORDINATED TO Zr

DOI: 10.1246/cl.1981.671

Source and publish data:

Chemistry Letters p. 671 - 674 (1981)

Update date:2022-07-31

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Authors:

Yasuda, Hajime

Kajihara, Yasushi

Mashima, Kazushi

Nagasuna, Kinya

Nakamura, Akira

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Article abstract of DOI:10.1246/cl.1981.671

ZrCp2(isoprene) reacts with aliphatic aldehydes, ketones or nitriles regioselectively on C1-carbon of the isoprene moiety to give novel 2-oxa- or 2-aza-metallacycles which release alcohols or ketones respectively on hydrolysis.In contrast, ZrCH3(η^{1
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Full text of DOI:10.1246/cl.1981.671

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