Synthesis and Site-Specific Incorporation of a Bay-Region Cis Ring-Opened Tetrahydro Epoxide-Deoxyadenosine Adduct into a DNA Oligomer

DOI: 10.1021/jo00038a037

Source and publish data:

Journal of Organic Chemistry p. 3438 - 3443 (1992)

Update date:2022-08-05

Topics:

Authors:

Lakshman, Mahesh K.

Sayer, Jane M.

Jerina, Donald M.

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Article abstract of DOI:10.1021/jo00038a037

Chemical synthesis of the 1,2,3,4-tetrahydrophenanthrene 3,4-epoxide adducts resulting from benzylic, cis ring-opening of the epoxide by the exocyclic amino group of 2'-deoxyadenosine (dA) is described.The approach taken consists of coupling (+/-)-cis-3-h

Full text of DOI:10.1021/jo00038a037

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