Journal of the Chemical Society. Chemical communications p. 1235 - 1236 (1984)
Update date:2022-09-26
Topics:
Carruthers, William
Williams, Michael J.
Cox, Michael T.
Intramolecular amidomercuration of N-methoxycarbonyl-6-aminohept-1-ene and reaction of the resulting organomercurial with sodium borohydride in the presence of acrylonitrile or decen-3-one has been used to prepare trans-2,6-dialkylpiperidines, including solenopsin A, a constituent of the venom of the fire-ant.
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