Novel palladium and platinum carbene-complexes containing dithiocarbonate ligand [M(PPh3) {η2(S,S)-S2CO]-{C(SR)(NMe2)}] formed via alkyl migration of O-alkyldithiocarbonate to thiocarbamoyl ligand

DOI: 10.1039/b305374a

Source and publish data:

Dalton Transactions p. 2810 - 2812 (2003)

Update date:2022-08-03

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Authors:

Yih, Kuang-Hway

Lee, Gene-Hsiang

Wang, Yu

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Article abstract of DOI:10.1039/b305374a

The first example of alkyl migration of O-alkyldithiocarbonate to thiocarbamoyl ligand results in carbene-complexes [M(PPh₃){η²(S,S)-S₂CO] {C(SR)(NMe₂)}] (M = Pd, Pt; R = Me, Et) from the reactions of [M(η²

Full text of DOI:10.1039/b305374a

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