Carbon-Carbon Bond Formation between α-Halogenoketones and Aldehydes Promoted by Cerium(III) Iodide or Cerium(III) Chloride-Sodium Iodide

DOI: 10.1039/c39850000777

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 777 - 778 (1985)

Update date:2022-08-05

Topics:

Authors:

Fukuzawa, Shin-ichi

Fujinami, Tatsuo

Sakai, Shizuyoshi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850000777

α-Halogenoketones react with aldehydes to form α,β-unsaturated ketones accompanied by dehalogenation in the presence of cerium(III) iodide, but the use of cerium(III) chloride-sodium iodide results in the formation of β-keto alcohols.

Full text of DOI:10.1039/c39850000777

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:2,4,8-Decatrien-1-one, 5,9-dimethyl-1-phenyl-

Cas No:65562-84-7

R&D Labs maybe for 65562-84-7

Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Wansheng

Contact:86-21-31200601

Address:Room1618,FangzhengDaSha,No.1122 Xinjinqiao Road,Pudong New District,Shanghai ,China
Shanghai Forever Synthesis Co.,Ltd.

Contact:021-61124658

Address:Zhoukang Road,Pudong New District,Shanghai,China
Geen Chemical Technology Co., Ltd

Contact:86-769-21660847

Address:1408, Yingfeng Commercial Center, Nancheng District

Relevant to this article

Conjugated and Cross-Conjugated ?-Extended Cycloproparanes with dithiole and Cyclopentadiene Functionality

Doi:10.1002/ejoc.200300619
(2004)
Reactions of Iron Atoms with Benzene and Cyclohexadienes in Argon Matrices: Iron-Benzene Complexes and Photolytic Dehydrogenation of Cyclohexadiene

Doi:10.1021/ja00281a028
(1986)
2,4,6-trialkylphenyl-2H-phospholes from slightly aromatic 1H-phospholes and their use in [4 + 2] cycloaddition reactions

Doi:10.1002/hc.10151
(2003)
Synthesis of 2-Aryl-2 H-benzotrizoles from azobenzenes and N-sulfonyl azides through sequential rhodium-catalyzed amidation and oxidation in one pot

Doi:10.1021/ol501250t
(2014)
FLUOROCARBON DERIVATIVES OF NITROGEN. PART 10. PREPARATION OF HEPTAFLUORO- AND 1-CHLOROHEXAFLUORO-2-NITROSOPROPANE, AND CONVERSION OF THE LATTER TO CHLOROPENTAFLUOROACETONE OXIME

Doi:10.1016/S0022-1139(00)85122-2
(1984)
Doi:10.1021/ja00472a051
(1978)

Article Doi