Sterically Hindered Lithium Dialkylamides; A Novel Synthesis of Lithium Dialkylamides from N-t-Alkyl-N-benzylideneamines and the Isolation of Highly Hindered s-Alkyl-t-alkylamines

DOI: 10.1055/s-1985-31452

Source and publish data:

Synthesis p. 1138 - 1140 (1985)

Update date:2022-08-03

Topics: Synthesis Isolation Reactivity Steric hindrance Deprotonation Schiff Base Metalation Lithium dialkylamides Organolithium Reagents

Authors:

Cliffe, Ian A.

Crossley, Roger

Shepherd, Robin G.

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Article abstract of DOI:10.1055/s-1985-31452

The convenient synthesis of lithium amides from imines 1 and organolithium reagents, and the isolation of the related highly hindered dialkylamines 3 are described.

Full text of DOI:10.1055/s-1985-31452

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Product name:N-Benzylidene-t-amylamine

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