Chemistry Letters p. 471 - 474 (1989)
Update date:2022-08-04
Topics:
Yamashita, Hiroshi
Kobayashi, Toshi-aki
Hayashi, Teruyuki
Tanaka, Masato
Vaska-type complexes such as MCl(CO)L2 (M=Rh or Ir, L= tertiary phosphine) or the Wilkinson complex RhCl(PPh3)3 underwent halogen exchange reactions with halosilanes Me3SiX (X=Br, I) to give MX(CO)L2 or RhX(PPh3)3 respectively with the formation of Me3SiC
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