Novel Halogen Exchange Reactions between Halosilanes and Rh(I) or Ir(I) Complexes

DOI: 10.1246/cl.1989.471

Source and publish data:

Chemistry Letters p. 471 - 474 (1989)

Update date:2022-08-04

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Authors:

Yamashita, Hiroshi

Kobayashi, Toshi-aki

Hayashi, Teruyuki

Tanaka, Masato

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Article abstract of DOI:10.1246/cl.1989.471

Vaska-type complexes such as MCl(CO)L2 (M=Rh or Ir, L= tertiary phosphine) or the Wilkinson complex RhCl(PPh3)3 underwent halogen exchange reactions with halosilanes Me3SiX (X=Br, I) to give MX(CO)L2 or RhX(PPh3)3 respectively with the formation of Me3SiC

Full text of DOI:10.1246/cl.1989.471

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