6Li and 23Na NMR Spectroscopic Studies of Metalated Hydrazone Cryptates. Effects of Ion Triplet Formation on the Stereochemistry of Alkylation

DOI: 10.1021/ja00219a033

Source and publish data:

Journal of the American Chemical Society p. 3546 - 3553 (1988)

Update date:2022-08-02

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Authors:

Galiano-Roth, Angela S.

Collum, David B.

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Article abstract of DOI:10.1021/ja00219a033

Effects of cryptand complexing agents on the structure and reactivity of metalated N,N-dimethylhydrazones is described.Cyano-stabilized lithiated hydrazones are shown by ⁶Li NMR spectroscopy to form 1:1 complexes with C<2.1.1> (C<2.1.1> = 4,7,1

Full text of DOI:10.1021/ja00219a033

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