Tetrahedron p. 867 - 876 (1983)
Update date:2022-08-04
Burford, Clifford
Cooke, Frank
Roy, Glenn
Magnus, Philip
Treatment of chloromethyltrimethylsilane 1 with sec-BuLi at -78 deg produces chloromethyl(trimethylsilyl)lithium 4.Treatment of 4 with a wide range of aldehydes and ketones gives α,β-epoxytrimethylsilanes 5-28, which on acidic hydrolysis give homologated aldehydes.
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