Nucleophilic Esterolytic and Displacement Reactions of a Micellar Thiocholine Surfactant

DOI: 10.1021/ja00522a053

Source and publish data:

Journal of the American Chemical Society p. 754 - 762 (1980)

Update date:2022-09-26

Topics: Experimental nucleophilic Displacement Micellar Surfactant

Authors:

Moss, Robert A.

Bizzigotti, George O.

Huang, Ching-Wen

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Article abstract of DOI:10.1021/ja00522a053

The thiol-functionalized surfactant N-n-cetyl-N,N-dimethyl-N-(β-thioethyl)ammonium chloride, 4 (16-SH), was synthesized.Under micellar conditions at pH 7, excess micellar 16-SH cleaved p-nitrophenyl acetate (PNPA) with k_ψ^max = 2.16 s

Full text of DOI:10.1021/ja00522a053

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