1-Nitro-1-(phenylthio)propene as a New Nitro Olefin Reagent for 3-Methylfuran Annulation and Its Application to the Synthesis of Some Furanoterpenoids

DOI: 10.1021/jo01303a005

Source and publish data:

Journal of Organic Chemistry p. 2945 - 2950 (1980)

Update date:2022-09-26

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Authors:

Miyashita, Masaaki

Kumazawa, Toshiaki

Yoshikoshi, Akira

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Article abstract of DOI:10.1021/jo01303a005

1-Nitro-1-(phenylthio)propene (9) was synthesized from (phenylthio)acetic acid (6) in five steps.This nitro olefin reacted with dimedone (1) with KF catalysis to yield dihydrofurans 10a and 10b, both of which were converted to 3-methylfuran 13 on NaIO4 ox

Full text of DOI:10.1021/jo01303a005

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