1-Nitro-1-(phenylthio)propene as a New Nitro Olefin Reagent for 3-Methylfuran Annulation and Its Application to the Synthesis of Some Furanoterpenoids

DOI: 10.1021/jo01303a005

Source and publish data:

Journal of Organic Chemistry p. 2945 - 2950 (1980)

Update date:2022-09-26

Topics:

Authors:

Miyashita, Masaaki

Kumazawa, Toshiaki

Yoshikoshi, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01303a005

1-Nitro-1-(phenylthio)propene (9) was synthesized from (phenylthio)acetic acid (6) in five steps.This nitro olefin reacted with dimedone (1) with KF catalysis to yield dihydrofurans 10a and 10b, both of which were converted to 3-methylfuran 13 on NaIO4 ox

Full text of DOI:10.1021/jo01303a005

Products guided by the article

Product name:4(5H)-Benzofuranone, 6,7-dihydro-3,6,6-trimethyl-2-(phenylthio)-

Cas No:67808-94-0

R&D Labs maybe for 67808-94-0

jiangsu haian chemical co.,ltd.

Contact:86-513-15851283853

Address:No.99,Changjiang West Road,Haian County,Jiangsu Province,China
Weifang Arylchem Chemical Co., LTD

Contact:86-536-5217866

Address:Development Zone, Shouguang, Shandong Province
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China
Shanghai Balmxy Pharmaceutical Co., Ltd

Contact:0086-21-24206007

Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China
Henan Yellow River New Material Technology Co.Ltd.

website:http://www.yellowriverchem.com

Contact:0086-373-7278760

Address:Chengguan Town, Yuanyang County

Relevant to this article

Quinazolines. XXIII. The synthesis of 3,5 Diazatetracyclo [7,3,1,1,^7,11,0^1,6]tetradecanes (Adamantano [2,1-d]pyrimidines)

Doi:10.1071/CH9781769
(1978)
Synthetic and Theoretical Studies of Cyclobuta[1,2:3,4]dicyclopentene. Organocobalt Intermediates in the Construction of the Unsaturated Carbon Skeleton and Their Transformation into Novel Cobaltacyclic Complexes by C-C Insertion

Doi:10.1021/jo030368p
(2004)
Controlled delivery of theophylline: Chemistry of 7-acyl- and 7,7'-acylditheophylline derivatives

Doi:10.1002/jps.2600670806
(1978)
A mild access to γ- or δ-alkylidene lactones through gold catalysis

Doi:10.1016/j.tetlet.2006.06.129
(2006)
Reactivity of palladium(II) methyl complexes towards CO₂: Formation of carbonate complexes

Doi:10.1016/j.ica.2003.10.027
(2004)
Doi:10.1016/0040-4020(78)80186-0
(1978)

Article Doi