Cis,cis-Spiro[4.4]nonane-1,6-diol: A new chiral auxiliary for the asymmetric Diets-Alder reaction

DOI: 10.1016/S0957-4166(96)00459-4

Source and publish data:

Tetrahedron Asymmetry p. 3521 - 3526 (1996)

Update date:2022-07-30

Topics:

Authors:

Nieman, James A.

Keay, Brian A.

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Article abstract of DOI:10.1016/S0957-4166(96)00459-4

The use of a mono-pivalate mano-acrylate bis-ester of (+)-1S,5S,6S-spiro[4.4]nonane-1,6-diol in an asymmetric Diels-Alder reaction with cyclopentadiene (2 equiv. BCl₃, -85°C, CH₂Cl₂) provided the expected endo bicycle addu

Full text of DOI:10.1016/S0957-4166(96)00459-4

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