New Synthetic Methods and Reagents for Complex Carbohydrates. II. Synthesis of 2-Acylamino-2-deoxy-D-glucopyranose Derivatives by Dimethylphosphinothioic Anhydride Method

Article abstract of DOI:10.1246/bcsj.61.4467

Dimethylphosphinothioic (Mpt) mixed anhydrides of carboxylic acids were found to be useful for N-acylation of 2-amino-2-deoxy-D-glucopyranose derivatives without protecting the hydroxyl functions.By this method, N-acylation of 2-amino-2-deoxy-D-glucopyran