Synthesis of β-D-Mannopyranosides and β-L-Rhamnopyranosides by Glycosidation at C-1

DOI: 10.1021/jo00319a016

Source and publish data:

Journal of Organic Chemistry p. 1121 - 1126 (1981)

Update date:2022-08-04

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Authors:

Srivastava, Vinai K.

Schuerch, Conrad

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Article abstract of DOI:10.1021/jo00319a016

A stereoselective synthesis of β-D-mannopyranosides and β-L-rhamnopyranosides has been achieved by glycosidation at C-1.Treatment of the 1-O-tosyl derivative 2 with 1 equiv of methanol in acetonitrile gave methyl 3,4,6-tri-O-benzyl-2-O-(methylsulfonyl)-β-

Full text of DOI:10.1021/jo00319a016

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