Inorganic Chemistry p. 3955 - 3960 (1982)
Update date:2022-07-29
Topics:
Carter, Willie J.
Kelland, John W.
Okrasinski, Stanley J.
Warner, Keith E.
Norton, Jack R.
Osmium hydrido alkyl carbonyl complexes cis-Os(CO)4(H)R (R = Me, Et) can be prepared by alkylation of [Os(CO)4H]- with the corresponding alkyl fluorosulfates. The thermal decomposition of these complexes gives dinuclear and trinuclear derivatives HOs2(CO)8R and ROs3(CO)12R. Other dinuclear complexes can be obtained from similar reactions of hydrides with alkyl carbonyl complexes. The course of the reaction of cis-Os(CO)4(H)CH3 with Ph3P depends upon the reaction conditions: with complete exclusion of air (Ph3P)Os(CO)4 and CH4 are obtained, whereas small amounts of air induce the rapid operation of a radical-chain substitution mechanism and the formation of Os(CO)3(PPh3)(H)CH3.
Shanghai Yanchu chemicals Co., Ltd
website:http://www.yanchuchem.com
Contact:0086 18601657701
Address:Room 1292, Building NO. 2, Lane 65, Huandong 1st Rd, Fengjing Town, Jinshan Distriction, shanghai
Jinan Jiaquan Chemical Co.,Ltd
Contact:+86-531-62318366
Address:Room 502 of Yidonghuayuan No.601 Huaxin Road Licheng District Jinan China
website:http://www.tcfinechem.com/
Contact:18681346930
Address:baifu town,whou district
Shanghai shibo Chemical Co., Ltd
Contact:+86-021-60753516
Address:688 Qiushi Road, Jinshan High-tech Park, Shanghai, China,201512
Tianjin Tongde Biological Technology Co., Ltd.
Contact:86-22-23309138
Address:Room 402, bulidingE3 Detection certification park, XiQingDistrict, Tianjin City
Doi:10.1016/S0957-4166(97)00589-2
(1997)Doi:10.1039/b809937e
(2008)Doi:10.1016/S0022-328X(00)82040-9
(1978)Doi:10.1002/jps.2600671042
(1978)Doi:10.1021/jm00210a023
(1978)Doi:10.1039/d0cy02312d
(2021)
