METALLATION OF ALIPHATIC CARBON ATOMS II, SYNTHESES AND CHARACTERIZATION OF THE CYCLOPALLADATED COMPLEXES OF N,N-DIMETHYLNEOPENTYLAMINE

Article abstract of DOI:10.1016/0022-328X(85)88104-3

N,N-Dimethyneopentylamine reacts with Pd(MeCO2)2 to give a novel trinuclear cyclopalladated complex *0.5C6H6 (I).The reaction of I with PPh3 affords both trans (III) .The reaction of III with LiCl yields a mononuclear cyclopalladated complex, (IV).