Helvetica Chimica Acta p. 1196 - 1203 (1985)
Update date:2022-08-04
Topics:
Chalais, Stephane
Cornelis, Andre
Gerstmans, Andre
Kolodziejski, Waclaw
Laszlo, Pierre
et al.
Multiple chlorinations and arylations at the tertiary positions of adamantane are promoted by FeCl3-doped K10 montmorillonite in CCl4 or in aromatic solvents.The process, remarkably easy implement, can be tailored to selective formation of monosubstituted 1-adamantyl derivatives or 1,3-disubstituted adamantanes.The process achieves alkylation at the meta- and para-positions of toluene leading to a purely statistical distribution and displays no substrate specificity in competition experiments between toluene and benzene.
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