CONFIGURATIONALLY AND CONFORMATIONALLY HOMOGENEOUS CYCLIC N-ARYL SULFIMIDES-IV. SYNTHESIS, CONFIGURATION AND STEREOCHEMISTRY OF THE REARRANGEMENT OF 1,3-DI-THIANE-1-N-p-CHLOROPHENYLIMIDES

Article abstract of DOI:10.1016/0040-4020(80)80041-X

1,3-Dithiane-1-N-p-chlorophenylimides (1,4-9) were prepared and their configuration and conformation was determined by (1)H and (13)C NMR.The compounds were rearranged to the corresponding 2-(2'-amino-5'-chlorophenyl)-1,3-dithianes (1U,4U-9U).The rearrang