Archiv der Pharmazie p. 301 - 305 (1995)
Update date:2022-08-05
Topics:
Wunsch
Nerdinger
Starting from vanillin (5a) a facile and high yielding procedure for the preparation of the donor substituted (2-bromophenyl)- and (2-iodophenyl)-acetaldehyde acetals 13c and 16c is described. Homologization of O-benzylvanillin to obtain the phenylacetaldehyde acetal 15c succeeds by Wittig reaction with the phosphonium chloride 11 and subsequent addition of methanol. 15c is brominated with pyridinium bromide perbromide in methanol to yield the bromo acetal 13c in 65% yield from vanillin. Iodination of 15c with iodine and iodic acid leads to the iodo acetal 16c.
View MoreContact:+91 9963263336
Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)
Contact:22-58516360
Address:tianjin
website:http://www.simagchem.com
Contact:+86-592-2680277
Address:21/F Hualong Office Building,No.6 Hubin East Road, Xiamen,China
Valiant Fine Chemicals Co., Ltd.
Contact:+86 535 6101878/6374484
Address:11 Wuzhishan Rd.,YTETDZ,Yantai,264006,Shandong,China
Zhejiang Genebest Pharmaceutical Co.,Ltd.
Contact:0086-571-63532866
Address:No.1 Jinboshi Rd Lishan Town Fuyang City Zhejiang Province China
Doi:10.1055/s-0028-1088127
(2009)Doi:10.1021/ja01239a014
(1944)Doi:10.1016/j.biochi.2010.04.022
(2010)Doi:10.1016/0040-4020(96)00414-0
(1996)Doi:10.1039/b400790p
(2004)Doi:10.1016/S0040-4039(02)01067-5
(2002)
