Tetrahedron Letters p. 3035 - 3038 (1996)
Update date:2022-08-02
Topics: Diastereoselectivity Hydride Transfer Aromatic Aldehyde Formation of Titanium Alkoxide Intramolecular Pinacol Reaction
Clerici, Angelo
Clerici, Laura
Porta, Ombretta
Aromatic aldehydes are stereoselectively coupled to dl-hydrobenzoins on treatment with anhydrous TiCl3/CH2Cl2 solution at room re. The observed stereochemistry is briefly discussed in terms of Ti(IV)-bridging control.
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