A highly dl-stereoselective pinacolization of aromatic aldehydes mediated by titanium trichloride in dichloromethane

DOI: 10.1016/0040-4039(96)00462-5

Source and publish data:

Tetrahedron Letters p. 3035 - 3038 (1996)

Update date:2022-08-02

Topics: Diastereoselectivity Hydride Transfer Aromatic Aldehyde

Authors:

Clerici, Angelo

Clerici, Laura

Porta, Ombretta

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Article abstract of DOI:10.1016/0040-4039(96)00462-5

Aromatic aldehydes are stereoselectively coupled to dl-hydrobenzoins on treatment with anhydrous TiCl₃/CH₂Cl₂ solution at room re. The observed stereochemistry is briefly discussed in terms of Ti(IV)-bridging control.

Full text of DOI:10.1016/0040-4039(96)00462-5

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