Tetrahedron p. 3405 - 3412 (1988)
Update date:2022-08-04
Topics:
Hill, Richard K.
McKinnie, B. Gary
Conley, Robert T.
Darby, Paul S.
Halbeek, Herman van
Holt, Elizabeth M.
Heating camphor oxime with PPA affords, besides the known fragmentation products isoaminocamphor (4) and β-campholenonitrile (13), four isomeric ketones C10H14O resulting from intramolecular acylation of the intermediate α-campholenonitrile (3).The ketones have been identified as 5-ketocamphene (6), 6-ketocamphene (8), tricyclenone (9), and endo-2,4-dimethylbicyclo<3.2.1>oct-2-ene-7-one (14).The latter results from a novel ring expansion, probably by way of a protonated cyclopropane.
View MoreNingbo Tide Imp. & Exp. Co., Ltd.
Contact:+86-571-8993 7933; +86-571-8993 6453
Address:7/F Anno Domini Building, Tower South, 8 Qiu Shi Road,Hangzhou,China.
Improve Medical Technology(Nanxiong) Co., Ltd
Contact:86-751-3836997
Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China
Contact:+86-25-52346955
Address:199,JIANYE ROAD,NANJING,CHINA
Shenyang Mole pharmaceutical Technology Development Co.,Ltd
Contact:+86-24-31204918/13889278616
Address:No.44, wanliutang road, shenhe District of Shenyang
Puyang Huicheng Electronic Material Co., Ltd
website:http://huichengchem.weba.testwebsite.cn/index_en.html
Contact:+86-393-8910800
Address:West Section Shengli Road, Puyang457000, China
Doi:10.1039/c39790000212
(1979)Doi:10.1016/j.tetasy.2011.10.003
(2011)Doi:10.1021/jo00250a033
(1988)Doi:10.1016/0039-128X(76)90079-9
(1976)Doi:10.1039/b313746e
(2004)Doi:10.1016/j.tetlet.2004.04.031
(2004)
