STEREOCHEMISTRY OF THE FLUORIDE CATALYZED ALDOL REACTION OF ENOL SILYL ETHERS. EVIDENCE FOR ANOTHER NON-CHELATE TRANSITION STATE

DOI: 10.1016/S0040-4039(00)86713-1

Source and publish data:

Tetrahedron Letters p. 2207 - 2210 (1988)

Update date:2022-08-02

Topics:

Authors:

Nakamura, Eiichi

Yamago, Shigeru

Machii, Daisuke

Kuwajima, Isao

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Article abstract of DOI:10.1016/S0040-4039(00)86713-1

Stereochemistry of the tetrabutylammonium fluoride catalyzed aldol reaction of enol silyl ethers was examined for both tri- and tetra-substitued enolates to find that the previous "extended, non-chelate" transition model (A) applicable only for enolates w

Full text of DOI:10.1016/S0040-4039(00)86713-1

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