Journal of the American Chemical Society p. 3049 - 3056 (1981)
Update date:2022-08-02
Topics:
Brough, Lawrence F.
West, Robert
The cyclic permethylpolysilanes (Me2Si)n, where n = 5-35, are all formed when dimethyldichlorosilane (Me2SiCl2) is added slowly to sodium-potassium (Na/K) alloy in tetrahydrofuran (THF).NMR, UV, and vibrational spectra are reported for compounds n = 5-19.The 13C NMR and 1H NMR spectra are explained in terms of methyl-methyl group interactions.Raman and IR spectra are assigned and partially explained on the basis of a standing wave model.
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