Tetrahedron Letters p. 4413 - 4416 (1981)
Update date:2022-08-03
Topics:
Suzuki, M.
Oda, Y.
Noyori, R.
Reaction of 1,3-diene 1,4-epiperoxides with Pd(PPh3)4 catalyst forms the corresponding 4-hydroxy enones, syn diepoxides, and 1,4-diols as the major products.The results are interpreted as being due to competing Pd(O)/ Pd(II) and Pd(O)/ Pd(I) exchange mechanisms.
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