Research on Chemical Intermediates p. 5387 - 5394 (2016)
Update date:2022-08-03
Topics:
Zhou, De-Jun
Yin, Shu-Qiang
Fan, Yun-Chang
Wang, Qiang
2,6-Diiododiaryl ethers are not only useful blocks to construct substituted diaryl ethers but are also characteristic drug precursors. In this research, a one-pot tandem oxidation of phenols substituted with electron-withdrawing group at the para position by excess diacetoxyiodobenzene is proven as a novel and efficient method for preparing 2,6-diiododiaryl ethers. Using this method, three new 2,6-diiododiaryl ethers, namely, methyl 3,5-diiodo-2-methoxy-4-phenoxybenzoate (2), methyl 3,5-diiodo-4-phenoxybenzoate (6), and 1-(2,6-diiodo-4-nitrophenoxy)benzene (7) were readily obtained from the corresponding phenols, and the yields were good.
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Doi:10.1016/0040-4020(79)80090-3
(1979)Doi:10.1016/j.poly.2004.03.009
(2004)Doi:10.1021/ic50205a029
(1980)Doi:10.1016/0040-4039(84)80029-5
(1984)Doi:10.1021/jo00298a066
(1990)Doi:10.1021/ja00517a038
(1979)