Journal of the American Chemical Society p. 90 - 96 (1983)
Update date:2022-08-02
Topics:
Katritzky, Alan R.
Kashmiri, M. Akram
Ville, George Z. de
Patel, Ranjan C.
The C-alkylation of 2-nitropropanide by N-substituted pyridiniums is first order in each reactant in Me2SO.The effect on the rate of temperature , N substituent, leaving group, and nucleophile was studied quantitatively.Overall, the evidence excludes an SN2 displacement and suggests that the reactions proceed by a free radical nonchain mechanism.
View Morewebsite:http://www.dulynet.com/
Contact:025-84699383 -8003
Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
TIANJIN NORTH JINHENG CHEMICAL PLANT.
Contact:0086-22-59952083
Address:DongShigu Country In JiXian TianJin China
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd
Contact:0086-10-64430626
Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
Pure Chemistry Scientific Inc.
Contact:+1-857-366-7588
Address:14905 SW freeway street #232, Sugarland, TX 77478, USA
Anhui Xinyuan Technology Co.,Ltd
Contact:0086-559-3515800
Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Doi:10.1021/jo01294a006
(1980)Doi:10.1016/S0020-1693(00)82550-5
(1983)Doi:10.1021/ja01167a084
(1950)Doi:10.1021/ja01196a056
(1947)Doi:10.1002/chem.201402833
(2014)Doi:10.1021/jo01296a025
(1980)
