Journal of the American Chemical Society p. 90 - 96 (1983)
Update date:2022-08-02
Topics:
Katritzky, Alan R.
Kashmiri, M. Akram
Ville, George Z. de
Patel, Ranjan C.
The C-alkylation of 2-nitropropanide by N-substituted pyridiniums is first order in each reactant in Me2SO.The effect on the rate of temperature , N substituent, leaving group, and nucleophile was studied quantitatively.Overall, the evidence excludes an SN2 displacement and suggests that the reactions proceed by a free radical nonchain mechanism.
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