A dinuclear triple bonded Ru-Ru compound: preparation and crystal structure of μ,μ'-1,2-phenylenediimine-(N,N')-dicarbonylbis(triphenylphosphine)diruthenium(Ru-Ru) (I)

DOI: 10.1016/0022-328X(87)80217-6

Source and publish data:

Journal of Organometallic Chemistry p. C43 - C46 (1987)

Update date:2022-08-05

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Authors:

Anillo, Adela

Riera, Victor

Obeso-Rosete, Ricardo

Font-Altaba, Manuel

Solans, Xavier

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Article abstract of DOI:10.1016/0022-328X(87)80217-6

Reaction of (PPh3)3> (1) with CO in toluene at room temperature affords as one of the products the dinuclear complex syn-(CO)2(PPh3)2> (2).The crystal structure of (2) reveals it to be an unsaturated bimetallic species, with two Ru(CO)(PPh3) moieties bridged by an 8e^- donor η²-diimine ligand in a tetrahedral-like fashion and involving a triple Ru-Ru bond.

Full text of DOI:10.1016/0022-328X(87)80217-6

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