Russian Chemical Bulletin p. 857 - 861 (1994)
Update date:2022-08-05
Topics:
Nikolaeva, S. N.
Zolotareva, A. S.
Ponomarev, S. V.
Petrosyan, V. S.
Dialkylamino- and alkoxytrialkylstannanes have been studied as N- and O-nucleophilic reagents in substitution reactions at the B-Br bond.The previously unknown bis(dialkylamino)- and dialkoxyboryl trialkylsilyl ketenes were synthesized.Some peculiarities of the reactivity of these compounds have been studied. - Key words: dialkylaminotrialkylstannane, alkoxytrialkylstannane, synthesis; borylsilyl ketene, methanolysis, aminolysis.
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