Inorganic Chemistry p. 1774 - 1779 (1992)
Update date:2022-08-04
Topics:
Rustad
Gregory
A spectrophotometric study of mixed-metal dimers in vapors formed by reaction of Al, Au, and Cl2 is presented. The absorbance of fully vaporized mixtures as well as the gas phase in equilibrium with Au(s) has been observed at various concentrations of Al2Cl6 and Cl2. While AlAuCl6(g) appears to be the dominant mixed-metal dimer, evidence is found suggesting the presence of molecules containing less chlorine, such as AlAuCl5(g). Assuming both AlAuCl6(g) and AlAuCl5(g) are present, thermodynamic properties and UV-visible absorption spectra are derived.
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