Thermal Isomerization of Allyl-Substituted Cyclopropenes. An Example of a Nonsynchronous Cope Rearrangement

DOI: 10.1021/ja00528a047

Source and publish data:

Journal of the American Chemical Society p. 2797 - 2806 (1980)

Update date:2022-08-04

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Authors:

Padwa, Albert

Blacklock, Thomas J.

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Article abstract of DOI:10.1021/ja00528a047

The thermal Cope rearrangement of a number of allyl-substituted cyclopropenes has been studied in mechanistic detail.Thermolysis of 1,2-diphenyl-3-allyl-3-methylcyclopropene produced an equilibrium mixture of recovered starting material (35percent), 1,3-d

Full text of DOI:10.1021/ja00528a047

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