SYNTHESIS OF 1-O-β-D-GLUCOPYRANOSYL-1L-(1,3,4/2,6)-4-AMINO-6-HYDROXYMETHYL-1,2,3-CYCLOHEXANETRIOL. ON THE STRUCTURE OF THE ANTIBIOTIC, VALIDAMYCIN A

Article abstract of DOI:10.1246/cl.1980.139

1-O-β-D-Glucopyranosyl-1L-1,3,4/2,6)-4-amino-6-hydroxymethyl-1,2,3-cyclohexanetriol (12) was synthesized and found to be identical with β-D-glucopyranosyl-validamine derived from validamycin A.The position at which validamine moiety was substituted with D