Syntheses of α-fluoro-α,β-unsaturated thioamides and thiazolines from a fluorophosphonodithioacetate

Article abstract of DOI:10.1021/jo049560x

A high-yielding synthesis of methyl fluoro(diethoxyphosphono)dithioacetate starting from its difluorinated analogue is reported. Fluorophosphonothioacetamides and -methylthiazolines, prepared from this new dithioester, have been successfully transformed i