A SYNTHESIS OF (+/-)-Δ2-α-LYCOREN-7-ONE, THE KEY INTERMEDIATE FOR THE TOTAL SYNTHESIS OF (+/-)-LYCORINE

DOI: 10.1016/S0040-4020(01)91130-5

Source and publish data:

Tetrahedron p. 1783 - 1790 (1984)

Update date:2022-08-03

Topics: Synthesis Total synthesis Intermediate Chemical Reaction

Authors:

Umezawa, Bunsuke

Hoshino, Osamu

Sawaki, Shohei

Sashida, Haruki

Mori, Kazuhiko

et al. et al.

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Article abstract of DOI:10.1016/S0040-4020(01)91130-5

(+/-)-α-Lycoran-3,5-dione (14a) was prepared from octahydrophenanthridin-3-one (8b) obtained by two methods starting from 5-aryl-4-nitrocyclohaxane (2) and 1-hydroxy-2-aryl-5-oxo-cyclohexanecarboxylic acid (10), both of which were prepared by the Diels-Al

Full text of DOI:10.1016/S0040-4020(01)91130-5

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Product name:Acetic acid (3aS,12bR,12cS)-5-oxo-1,3a,4,5,12b,12c-hexahydro-7H-[1,3]dioxolo[4,5-j]pyrrolo[3,2,1-de]phenanthridin-2-yl ester

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