Tetrahedron p. 1783 - 1790 (1984)
Update date:2022-08-03
Topics: Synthesis Total synthesis Intermediate Chemical Reaction
Umezawa, Bunsuke
Hoshino, Osamu
Sawaki, Shohei
Sashida, Haruki
Mori, Kazuhiko
et al.
(+/-)-α-Lycoran-3,5-dione (14a) was prepared from octahydrophenanthridin-3-one (8b) obtained by two methods starting from 5-aryl-4-nitrocyclohaxane (2) and 1-hydroxy-2-aryl-5-oxo-cyclohexanecarboxylic acid (10), both of which were prepared by the Diels-Al
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