Bulletin of the Chemical Society of Japan p. 775 - 784 (1980)
Update date:2022-08-02
Topics:
Oae, Shigeru
Shinhama, Koichi
Fujimori, Ken
Kim, Yong Hae
Several new sulfenyl or sulfonyl derivatives, thionitrates (RSNO2), sulfonyl nitrites (RSO2NO), were successfully isolated by treating corresponding thiols and sulfinic acids with dinitrogen tetraoxide (N2O4).Spectroscopic data of both stable and many rather unstable compounds were determined and compared with those of corresponding alkyl nitrites (RONO) or alkyl nitrates (RONO2).Chemical reactivities of these uncommon, novel S-nitroso and S-nitro compounds were investigated.
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