Recueil des Travaux Chimiques des Pays-Bas p. 230 - 236 (1988)
Update date:2022-08-04
Topics:
Suzuki, M.
Watanabe, A.
Noyori, R.
In the presence of catalytic amounts of tetrakis(triphenylphosphine)palladium(0) and 1,2-bis(diphenylphosphino)ethane, α,β-epoxy ketones isomerize to the corresponding β-diketones in high yields.Both open-chain and cyclic substrates can be used.Possible reaction mechanisms are discussed.
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Doi:10.1016/S0040-4039(00)77592-7
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