Metal-Catalyzed Organic Photoreactions. Titanium(IV) Chloride Catalyzed Photoreaction of Saturated Ketones with Methanol and Its Application to the Synthesis of Frontalin

DOI: 10.1021/jo01307a011

Source and publish data:

Journal of Organic Chemistry p. 3778 - 3782 (1980)

Update date:2022-08-04

Topics:

Authors:

Sato, Tadashi

Kaneko, Hirokazu

Yamaguchi, Shinichi

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Article abstract of DOI:10.1021/jo01307a011

Photoreaction of acyclic and cyclic saturated ketones in methanol in the presence of TiCl4 afforded 1,2-diols as the main products.The effect of the substituents on the stereochemical course of the photoreaction was examined with substituted cyclohexanones.Further, the present reaction was applied for the synthesis of a pheromone, frontalin.

Full text of DOI:10.1021/jo01307a011

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