SYNTHESIS OF CROWN ETHER DYES.

Article abstract of DOI:10.1246/bcsj.53.1550

Crown ether dyes were synthesized in order to develop photometric reagents which are highly selective to alkali and alkaline earth metals. They contain dissociable protons attached to the chromophores of crown ether molecule. Their extraction behavior for alkali and alkaline earth metal ions as neutral complex was examined. The dyes extract potassium and alkalin earth metals, respectively. Dyes with picrylamino chromosphore are effective for extractive photometric determination of potassium. A molecular design of colorimetric reagents is discussed on the basis of crown ethers.